Small sets of chemical kinetics equations for reactions with the water monomers and dimers are solved. Equilibrium complex concentration distribution as a function of the complex dimension at the number of monomers in a complex up to 10 shows a nonmonotonic form for some values of the total monomer unit number and reaction rates with tetramers and dimers.
Small sets of chemical kinetics equations describing the cluster formation of complexes in water vapor are investigated. Sets of equations for N≤10 are solved by means of the implicit Eulerian method of the first order of accuracy for the model systems with unit rate constants and with real rate constants available in the literature. The character of cluster concentration distribution in the steady state as a function of their dimensions is changed at variations of the total monomer number A.
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