The Terahertz Time Domain Reflection Spectroscopy (THz-TDS) method of paint layer diagnostics is a non-contact
electromagnetic technique analogous to pulsed-ultrasound with the added capability of spectroscopic characterization.
The THz-TDS sensor emits a near-single cycle electromagnetic pulse with a bandwidth from 0.1 to 3 THz. This wide
bandwidth pulse is focused on the coating, and echo pulses are generated from each interface (air-coating, layer-layer,
coating-substrate). In this paper, the THz-TDS method is applied to specialty aircraft coatings. The THz-TDS method is
able to penetrate the whole coating stack and sample the properties of each layer. Because the reflected pulses from
individual layers typically overlap in time, the complex permittivity function and thickness of each layer is determined
by a best fit of the measured reflection (either in time or frequency domain) to a layered model of the paint. The THz-
TDS method is applied to specialty coatings prior to and during accelerated aging on a series of test coupons. The
coupons are also examined during aging using ATR (attenuated total reflectance)-FTIR spectroscopy, Raman scattering
spectroscopy, and Scanning Electron Microscopy (SEM) to ascertain, quantify, and understand the breakdown
mechanisms of the coatings. In addition, the same samples are characterized using THz-TDS techniques to determine if
the THz-TDS method can be utilized as a non-destructive evaluation technique to sense degradation of the coatings. Our
results suggest that the degradation mechanism begins in the top coat layer. In this layer, 254 nm UV illumination in
combination with the presence of moisture works partially with oxides as catalysts to decompose the polymer matrix
thereby creating porosity in the top coat layer. Since the catalytic effect is partial, loss of the oxides by chemical reaction
can also occur. As the topcoat layer becomes more porous, it allows water vapor to permeate the topcoat layer and
interact with the rain erosion layer via carbonization of the polymer matrix in the rain erosion layer. The presence of the
salt accelerates the pitting degradation. The goal of this paper is to determine if THz-TDS can be used to sense
degradation of the coating.
In the last decade, terahertz-mode imaging has received increased attention for non-destructive testing applica-
tions due to its ability to penetrate many materials while maintaining a small wavelength. This paper describes
a model-based reconstruction algorithm that is able to image defects in the spray-on foam insulation (SOFI)
used in aerospace applications that has been sprayed on a re
ective metal hull. In this situation, X-ray based
imaging is infeasible since only one side of the hull is accessible in
ight.
This paper models the object as a grid of materials, each section of which has a constant index of refraction.
The delay between the transmission and reception of a THz pulse is related to the integral of the index of
refraction along the pulse's path, and we adapt computed tomography (CT) methods to reconstruct an image
of an object's index of refraction.
We present the results of our reconstruction method using real data of the timing of THz pulses passing
through a block of SOFI with holes of a known location and radius. The resulting image of the block has a low
level of noise, but contains artifacts due to the limited angular range of one-sided imaging and due to the narrow
beam approximation used in the forward model.
A portable video rate time-domain terahertz (TD-THz) reflection line-scanner suitable for aerospace destructive
examination (NDE) and security inspection is described. The imager scans a line 6 inches wide and collects a TD-THz
cross-sectional "B-scan" of the sub-surface structure at rates up to 30 Hz. The imager is hand-held. By rolling the
scanner over surface, a radiographic two dimensional "C-Scan" image can be stitched together from the individual lines
at a rate of 1-4 inches per second (depending on desired resolution). The case is 8.7 in. wide (12.9 in. with wheels), 12.5
in. long, and 7.9 in. high. The weight is approximately 11 lbs. Example images taken with the scanner of radome THz
NDE are shown.
Time domain terahertz (TD-THz) reflection imaging tomography can be used to investigate the laminar structure of
objects. In a monostatic configuration, a sequence of pulses is generated by reflection from each discontinuity in index
of refraction. Through analysis of the return pulses, the material absorption and index of refraction properties of each
layer can be determined. TD-THz reflection tomography can be used to precisely measure the thickness of coatings
such as yttria stabilized zirconia (YSZ) thermal barrier coatings (TBC) on aircraft engine turbine blades; paint on
aircraft, ships, and cars; and other thin film measurement applications. In each of these cases, precise determination of
the optical delay of the TD-THz pulses is required with as little as sub-10 femtosecond precision for pulses which can be
greater than 500 fs in duration. We present a method to accurately measure optical delay between layers where the
pulses are fit to a reference template. These are demonstrated to achieve micron scale accuracy in coating thickness. As
an example, TD-THz non destructive evaluation (NDE) imaging is used to two-dimensionally map the thickness of YSZ
TBCs on aircraft engine turbine blades. Indications of thermal degradation can be seen. The method is non-contact,
rapid, and requires no special preparation of the blade.
We demonstrate the location and identification of delaminations and water intrusion in advanced composite materials used in ground based radome panels, shelters and towers using time domain terahertz imaging. Water has a very high absorption in the THz spectral region in comparison to polymer foam and fiberglass, so the method is very sensitive to water intrusion. The sub-picosecond near single cycle electromagnetic images enabled identification of delaminations of the fiberglass shell and foam. We report a novel time domain terahertz non-destructive evaluation control system, which is suitably portable for applications such as field examination of radome composites.
Experimental results of homodyne terahertz interferometric 2-D imaging of RDX are presented. Continuous waves at
0.25-0.6 THz are used to obtain images of a C-4 sample at several THz frequencies. The performance of an N element
detector array is imitated by only one detector placed at N positions. The distance between the C-4 sample and the
detector array is ~30 cm. By taking interferometric images at several THz frequencies RDX can be recognized by the
spectral peak at 0.82 THz. Simulations of interferometric images of two point sources of spherical waves are presented.
The terahertz interferometric imaging method can be used in defense and security applications to detect concealed
weapons, explosives as well as chemical and biological agents.
Experimental results of two-dimensional homodyne terahertz interferometric imaging are presented. The
performance of an N element detector array is imitated by only one detector placed at N positions.
Continuous waves at 0.25-0.3 THz are used to detect concealed objects: a metal object and an RDX
sample. The terahertz interferometric imaging method can be used in defense and security applications to
detect concealed weapons, explosives as well as chemical and biological agents.
Experimental results of homodyne terahertz interferometric 1-D and 2-D imaging are presented. Continuous waves at 0.25-0.3 THz are used to detect a metal object behind a barrier. The performance of an N element detector array is imitated by only one detector placed at N positions. The reconstructed images are in a good agreement with theoretical predictions. The terahertz interferometric imaging method can be used in defense and security applications to detect concealed weapons, explosives as well as chemical and biological agents.
We demonstrate a large area time domain terahertz (THz) imaging system capable of scanning 1 meter square area in less than 20-100 minutes for several security applications. The detection of concealed explosives; metallic and non-metallic weapons (such as ceramic, plastic or composite guns and knives); and flammables in luggage, packages and personnel has been demonstrated. Transmission mode images of luggage containing threat items are discussed. Reflection mode images of luggage and personnel are discussed. Time domain THz images can be analyzed for 3 dimensional and volumetric information. Time domain THz images have advantages over coherent narrow band imaging methods, with freedom from standing wave artifacts and with greater ability to discard irrelevant or intervening reflections through time discrimination.
Recently, there has been a significant interest in employing Terahertz (THz) technology, spectroscopy and imaging for standoff detection applications. There are three prime motivations for this interest: (a) THz radiation can detect concealed weapons since many non-metallic, non-polar materials are transparent to THz radiation, (b) target compounds such as explosives, and bio/chemical weapons have characteristic THz spectra that can be used to identify these compounds and (c) THz radiation poses no health risk for scanning of people. This paper will provide an overview of THz standoff detection of explosives and weapons including discussions of effective range, spatial resolution, and other limitations. The THz approach will be compared to alternative detection modalities such as x-ray and millimeter wave imaging.
Terahertz imaging has the potential to reveal concealed explosives; metallic and non-metallic weapons (such as ceramic, plastic or composite guns and knives); flammables; biological agents; chemical weapons and other threats hidden in packages or on personnel. Time domain terahertz imaging can be employed in reflection mode to image with sub millimeter resolution. Previously, single pixel acquisition times for THz waveforms was typically 20 Hz with time records of approx 80 picoseconds, which typically restricted imaging time to hours for areas on the order of 1 square foot, limiting the field practicality of the equipment. We describe and demonstrate advanced imagers with 100 Hz --> 320 picosecond, and 4000 Hz -- 20 picosecond waveform records. These systems have been demonstrated to image >600 pixels/second from a single channel. Such a system, combined with a 32 channel linear THz array, could image a 1 square foot area with 1 mm resolution in <5 seconds, performing a shoe explosives detection image in a short period of time.
It has been suggested that interferometric/ synthetic aperture imaging techniques, when applied to the THz regime, can provide sufficient imaging resolution and spectral content to detect concealed explosives and other weapons from a standoff distance. The interferometric imaging method is demonstrated using CW THz generation and detection. Using this hardware, the reconstruction of THz images from a point source is emphasized and compared to theoretical predictions.
Terahertz imaging has shown great potential in several biomedical areas such as burn imaging, detection of skin cancer, and pharmaceutical tablet imaging. The development of each of these application has been limited by slow imaging speed (tens of minutes to hours) and small scan areas (less than 10 square centimeters). Elsewhere to date, the sample itself must be mechanically raster scanned due to the free space optical coupling of femtosecond laser pulses driving the terahertz generating and detecting elements. This paper reports on the development of a freely positionable fiber optic coupled terahertz transceiver which may be raster scanned over a stationary object. Image acquisition times of less than 8 minutes for a 20x20 cm area (400 sq cm area) raster scanning a terahertz transceiver over a stationary object; and of less than 1 minute for image acquisition with a movable object raster scanning the object have been demonstrated. High speed stationary imaging will allow the practical investigation on human and animal subjects.
The application of near-field interferometric imaging to the Terahertz frequency range for detection of concealed objects is discussed. A circular array architecture can be employed to compensate for near-field distortions and increase the field of view and depth of focus. The lateral and focusing errors of this imaging method are discussed as well as the trade-offs of interferometric imaging compared to a focal plane array architecture.
Terahertz Time domain spectroscopy (THz-TDS) can provide the optical response of a medium in both amplitude and phase. We show that such capability can enable a detail analysis of optical properties of biological sample. Such study is important for standoff detection of presence of biological sample, where a detail analysis is difficult if not possible due to a complicated system involved and multiple effects involved. We proposed a transfer function study of the response of such system.
Terahertz Time domain spectroscopy (THz -TDS ) can provide the optical response of a medium in both amplitude and phase. We show that such capability can enable a detail analysis of optical properties around a resonance regime. Such study is important for standoff detection of explosive material where numerous absorption peaks exist. We proposed a model where one can synthesize the optical properties with THz-TDS around the resonance regimes.
The imaging properties of planar, spherical, and circular interferometric imaging arrays are examined in the near-field region limit. In this region, spherical and circular array architectures can compensate for near-field distortions and increase the field of view and depth of focus. The application of near-field interferometric imaging to the Terahertz frequency range for detection of concealed objects is emphasized.
Terahertz imaging has the potential to reveal concealed explosives; metallic and non-metallic weapons (such as ceramic, plastic or composite guns and knives); flammables; biological agents; chemical weapons and other threats hidden in packages or on personnel. Because terahertz imaging employs safe non-ionizing radiation that penetrates clothing, people may be routinely scanned as well as packages. Time domain terahertz imaging can be employed in reflection mode to image beneath clothing with sub millimeter resolution. Fiber optic coupled terahertz transmitter and generator arrays can be constructed to more quickly objects such as shoes, or larger portions of the body. The application of commercially available time domain terahertz spectroscopy equipment to imaging through clothing on simulant personnel is shown to distinguish harmful from innocuous objects.
A non-invasive means to detect and characterize concealed agents of mass destruction in near real-time with a wide field-of-view is under development. The method employs spatial interferometric imaging of the characteristic transmission or reflection frequency spectrum in the Terahertz range. However, the successful (i.e. low false alarm rate) analysis of such images will depend on correct distinction of the true agent from non-lethal background signals. Neural networks are being trained to successfully distinguish images of explosives and bioagents from images of harmless items. Artificial neural networks are mathematical devices for modeling complex, non-linear relationships. Both multilayer perceptron and radial basis function neural network architectures are used to analyze these spectral images. Positive identifications are generally made, though, neural network performance does deteriorate with reduction in frequency information. Internal tolerances within the identification process can affect the outcome.
A proposed, non-invasive, means to detect and characterize concealed biological and explosive agents in near real-time with a wide field-of-view uses spatial imaging of their characteristic transmission or reflectivity wavelength spectrum in the Terahertz (THz) electro-magnetic range (0.1-3 THz). Neural network analyses of the THz spectra and images will provide the specificity of agent detection and reduce the frequency of false alarms. Artificial neural networks are mathematical devices for modeling complex, non-linear functionalities. The key to a successful neural network is adequate training with known input-output data. Important challenges in the research include identification of the preferred network structure (e.g. multi-layer perceptron), number of hidden nodes, training algorithm (e.g. back propagation), and determination of what type of THz spectral image pre-processing is needed prior to application of the network. Detector array images containing both spectral and spatial information are analyzed with the aid of the Neurosolutions(TM) commercial neural network software package.
Terahertz imaging has the potential to reveal concealed explosives; metallic and non-metallic weapons (such as ceramic, plastic or composite guns and knives); flammables; biological agents; chemical weapons and other threats hidden in packages or on personnel. Because terahertz imaging employs safe non-ionizing radiation that penetrates clothing, people may be routinely scanned as well as packages. Images can have sub-millimeter resolution, superior to longer wavelength techniques. Explosives, chemical weapons, and biological agents may posses a spectral fingerprint in the terahertz regime. The application of commercially available time domain terahertz spectroscopy equipment to imaging of concealed threats within packages is shown to penetrate common packing materials and clearly image common plastic and metal threat objects.
Terahertz imaging has been shown to be a powerful tool for analyzing a variety of materials. From the amount of water in a leaf over time to looking at the spectroscopic species in a flame, this technique shows great potential for commercial applications. However, in order to work in a commercial environment, the present free-space optical systems must be abandoned in favor of fiber-optic delivery. To this end, we have developed a compact, fiber-pigtailed terahertz imaging system that utilizes a hermetically sealed, photoconductive, transmitter and receiver. The receiver uses an integrated amplifier to obtain a 1000:1 S/N with only 1 mW of power on both the transmitter and receiver and with a one second integration time. This system has usable energy extending from 0.04 to 2 THz and has both a rapid (20 Hz) scanner for short, 40-ps, scans as well as a long rail for scans up to 1 ns. The system hardware is contained in a 1.5 cu. ft. box with fibers feeding both the transceiver units. These units can be configured into either a transmission or reflection mode depending on the user's application. An advanced software system controls the hardware, collects the data, and does image processing.
An account is given of the first infrared vibrational photon echo experiments conducted in liquids and a glasses. The experiments were performed on the CO stretching mode of the solute tungsten hexacarbonyl (W(CO)6) at approximately 5.05 micrometers (approximately 1980 cm-1) in the solvents 2-methytetrahydrofuran, and 2-methylpentane (2-MP). In 2-MP, it was possible to observe the photon echo decay at room temperature and follow the temperature dependence from room temperature to 10 K. The photon echo experiments were conducted using the Stanford superconducting-linear-accelerator-pumped Free Electron Laser as the source of tunable ps infrared pulses.
Intense tunable vibrational infrared pulses from a free-electron laser and from a laser-pumped optical parametric amplifier can be used to study molecular energy transfer in condensed phase systems. Specific examples discussed here are energy transfer at the active site of a protein, myoglobin, studied by infrared-infrared pump-probe techniques, and energy transfer in a high explosive, nitromethane, probed by infrared-pump, anti-Stokes Raman probe techniques.
The first infrared vibrational photon echo experiments conducted in a liquid and a glass are reported. The experiments were performed on the CO stretching mode of tungsten hexacarbonyl at 5.1 micrometers (1960 cm-1) in 2-methyltetrahydrofuran over the temperature range 300 K to 16 K using picosecond pulses from the free electron laser at Stanford University. In addition, the first vibrational population relaxation measurements spanning a temperature range that takes a system from a liquid to a supercooled liquid to a glass are reported.
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