Open Access
28 August 2013 High-sensitivity detection of trace gases using dynamic photoacoustic spectroscopy
Charles M. Wynn, Stephen T. Palmacci, Michelle L. Clark, Roderick R. Kunz
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Abstract
Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new form of photoacoustic spectroscopy that relies on a laser beam swept at the speed of sound to amplify an otherwise weak photoacoustic signal. We experimentally determine the sensitivity of this technique using trace quantities of SF 6 gas. A clutter-limited sensitivity of ∼100  ppt is estimated for an integration path of 0.43 m. Additionally, detection at ranges over 5 m using two different detection modalities is demonstrated: a parabolic microphone and a laser vibrometer. Its utility in detecting ammonia emanating from solid samples in an ambient environment is also demonstrated.
CC BY: © The Authors. Published by SPIE under a Creative Commons Attribution 4.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.
Charles M. Wynn, Stephen T. Palmacci, Michelle L. Clark, and Roderick R. Kunz "High-sensitivity detection of trace gases using dynamic photoacoustic spectroscopy," Optical Engineering 53(2), 021103 (28 August 2013). https://doi.org/10.1117/1.OE.53.2.021103
Published: 28 August 2013
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CITATIONS
Cited by 11 scholarly publications and 2 patents.
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KEYWORDS
Photoacoustic spectroscopy

Acoustics

Signal detection

Signal to noise ratio

Gases

Absorption

Solids

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