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TiNx films are deposited on glass in a modified dc planar
three-magnetron geometry. The ellipsometric and reflectance measurements
reveal the influence of the substrate bias and of the Ar:N2 partial
pressure ratio on the stoichiometry and optical properties of the films.
The stoichiometric structure is obtained for only certain bias voltage and
Ar:N2 ratio values. The value of the plasma energy wp confirmed the film
stoichiometry, as determined from x-ray diffractometry.
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Gabriela Pavelescu, Mariana Braic, Viorel Braic, Laura Melinte, Dorin Melinte, "Spectroellipsometric studies on TiNx films deposited on glass," Opt. Eng. 35(5) (1 May 1996) https://doi.org/10.1117/1.600625