In recent decades, GaN and related compounds gained prominence as top semiconductor materials for high-power, high-temperature optoelectronics, electronics, and power conversion. However, better substrate materials are still sought after despite extensive nitride research. Commonly used substrates like sapphire and silicon have high lattice mismatches with GaN, leading to challenges in heteroepitaxial growth.
A promising solution emerged with ScAlMgO4 (SCAM) proposed as a GaN growth substrate. SCAM offers several advantages:
i) Smaller lattice mismatch with GaN than sapphire, reducing dislocation density in grown structures.
ii) Matching thermal expansion coefficient with GaN along the a-axis, reducing residual strain.
iii) Easy cleavage along the c-plane, yielding atomically flat substrates without polishing.
iv) Ability to grow large SCAM crystals via the Chochralski method.
In this study1, we present experimental and theoretical investigations on the optical, electronic, and structural properties of ScAlMgO4. Our experimental techniques include variable angle spectroscopic ellipsometry, optical transmission, X-ray diffraction, scanning electron microscopy, and Raman spectrosco
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