Paper
13 September 2012 Water-soluble iridium phosphorescent complexes for OLED applications
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Abstract
Newly prepared water-soluble iridium phosphorescent complexes, trans-[Ir(ppy)(PAr3)2(H)L]0,+ (ppy = bidentate 2-phenylpyridinato anionic ligand; L= Cl (1), CO (2), CN- (3); H being trans to the nitrogen of ppy ligand; PAr3 (TPPTS) = P(m-C6H4SO3Na)3), have been synthesized and characterized. Those complexes containing water-soluble phosphine ligands can emit any color region as altering cyclometalated ligands in aqueous media with high quantum efficiencies. Even though these water-soluble phosphorescent iridium complexes can be the sensing probe for toxic CO gas and CN anion, they will be capable of promising materials in the solution processible OLED applications.
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Min-Sik Eum, Heekoo Yoon, and Tae Hyung Kim "Water-soluble iridium phosphorescent complexes for OLED applications", Proc. SPIE 8476, Organic Light Emitting Materials and Devices XVI, 847607 (13 September 2012); https://doi.org/10.1117/12.930183
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KEYWORDS
Carbon monoxide

Iridium

Organic light emitting diodes

Chlorine

Metals

Nitrogen

Hydrogen

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