Paper
19 February 1988 Invited Paper Photorefractive Effect In BaTiO3:Fe
C. Warde, D. Temple, P. G. Schunemann, R. S. Hathcock
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Abstract
High-purity BaTiO3 single crystals (with transition-metal ion impurity levels well below 1016 cm-3 ) and a series of iron-doped BaTiO3 crystals with iron concentrations ranging from 5 to 1000 ppm were grown. These crystals were annealed in oxidizing and reducing atmospheres and their photorefractive properties characterized. A thermodynamic defect model was used to predict changes in the valence state of the iron as a function of annealing temperature, oxygen partial pressure and iron concentration. It was found that the "pure" crystals were photorefractive and that the saturation diffraction efficiency of gratings established in both the doped and the undoped crystals increased when the crystals were annealed in reducing atmospheres, but did not scale with the concentration of iron in the crystals. The evidence suggests that variable-valent iron ions are not the dominant photorefractive centers in these samples.
© (1988) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
C. Warde, D. Temple, P. G. Schunemann, and R. S. Hathcock "Invited Paper Photorefractive Effect In BaTiO3:Fe", Proc. SPIE 0825, Spatial Light Modulators and Applications II, (19 February 1988); https://doi.org/10.1117/12.941991
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KEYWORDS
Crystals

Iron

Diffraction

Ferroelectric materials

Absorption

Diffraction gratings

Laser crystals

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