Polarizability functions of HF and HCI molecules

Michail A. Buldakov; Victor N. Cherepanov; Nataliya S. Nagornova

doi:10.1117/12.675209

21 April 2006 Polarizability functions of HF and HCI molecules

Michail A. Buldakov, Victor N. Cherepanov, Nataliya S. Nagornova

Proceedings Volume 6160, Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics; 61600A (2006) https://doi.org/10.1117/12.675209
Event: Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 2005, Tomsk, Russian Federation

Abstract

The semiempirical method of construction of the electronic polarizability functions for heteronuclear diatomic molecule in the piecewise-continuous form is discussed. The polarizability functions obtained have true asymptotic behaviour as for small as for large internuclear separations R and describe correctly the polarizability of a molecule in a vicinity of the equilibrium internuclear distance. To describe the polarizability functions for large separations, the DID interactions of atoms have been taken into account, and the exchange interactions of atoms have been considered by asymptotic methods. The method has been applied to calculate the polarizability functions of HF and HCI molecules in a range R ∈ [0,∞).

Citation Download Citation

Michail A. Buldakov, Victor N. Cherepanov, and Nataliya S. Nagornova "Polarizability functions of HF and HCI molecules", Proc. SPIE 6160, Twelfth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 61600A (21 April 2006); https://doi.org/10.1117/12.675209

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