CCI2 reactions with HCI, NO2 and O2

V. M. Freytes; J. Codnia; M. L. Azcarate

doi:10.1117/12.591552

21 October 2004 CCI₂ reactions with HCI, NO₂ and O₂

V. M. Freytes, J. Codnia, M. L. Azcarate

Proceedings Volume 5622, 5th Iberoamerican Meeting on Optics and 8th Latin American Meeting on Optics, Lasers, and Their Applications; (2004) https://doi.org/10.1117/12.591552
Event: 5th Iberoamerican Meeting on Optics and 8th Latin American Meeting on Optics, Lasers, and Their Applications, 2004, Porlamar, Venezuela

Abstract

The IR Multiphoton Dissociation (IRMPD) of CDCl₃ different gases was studied with the flash photolysis technique using a tunable CO₂ TEA laser tuned to the 10P(48) line. CDCl₃ samples were irradiated in the presence of HCl to analyze a possible recombination of the primary dissociation fragments CCl₂ and DCl. The IRMPD of CDCl₃ was also studied in mixtures of HCl/Ar, O₂/Ar and NO₂/Ar. In the experiences with added HCl, CHCl₃ was obtained as major product evidencing the existence of the CCl₂ and DCl recombination reaction. The dissociation probabilities per pulse obtained with the addition of different gases were compared.

Citation Download Citation

V. M. Freytes, J. Codnia, and M. L. Azcarate "CCI₂ reactions with HCI, NO₂ and O₂", Proc. SPIE 5622, 5th Iberoamerican Meeting on Optics and 8th Latin American Meeting on Optics, Lasers, and Their Applications, (21 October 2004); https://doi.org/10.1117/12.591552

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