Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions

Vladimir M. Mikhailov

doi:10.1117/12.375366

25 January 2000 Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions

Vladimir M. Mikhailov

Author Affiliations +

Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375366
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation

Abstract

The contribution have been devoted the construction of effective quadrupole coupling operator for quasidegenerate vibrational levels of polyatomic molecules and the reduction of the laser. The indeterminacy problem of the parameters in the effective vibrational-rotational H^eff_VR and quadrupole W_eff Hamiltonians for the cases of accidental resonances linked with various groupings of vibrational- rotational interactions (problem of grouping uncertainty) are considered. The problem of the reduction of H^eff equals H^eff_VR + W^eff is discussed. The case of the Coriolis-type, accidental resonances have been considered more detail. New representation of H^eff equals H^eff_VR + W^eff for isolated vibration levels in form of angular moments only is presented.

Citation Download Citation

Vladimir M. Mikhailov "Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375366

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available