Plastic deformation of the amorphous component in semicrystalline polymers

Z. Bartczak; Andrzej Galeski; A. S. Argon; R. E. Cohen

doi:10.1117/12.267200

18 February 1997 Plastic deformation of the amorphous component in semicrystalline polymers

Z. Bartczak, Andrzej Galeski, A. S. Argon, R. E. Cohen

Proceedings Volume 3095, X-Ray Investigations of Polymer Structures; (1997) https://doi.org/10.1117/12.267200
Event: X-Ray Investigations of Polymer Structures, 1996, Bielsko-Biala, Poland

Abstract

The molecular orientation of the amorphous components of semicrystalline high density polyethylene induced by plane strain compression was studied by wide angle X-Ray scattering measurements utilizing pole figure technique and separation of scattering provided by crystalline and amorphous component. It was found that the oriented amorphous component produced by large strain plastic deformation consist of the domains of extended chain segments closely packed in a 2D pseudohexagonal aggregation, separated by less ordered regions. The deformation leads to the formation of the texture of the amorphous component common for the whole sample. In this texture the direction of chains coincides with the direction of flow and one of (100) pseudo-planes of the pseudohexagonal structure in every domain is perpendicular to loading direction. It was suggested that the most important deformation mechanisms in the ordered amorphous component were the glide of the chain segments along their axes and slip of the pseudo-planes of ordered chains in the direction perpendicular to chain axis, both resembling the crystallographic slip processes. Such specific deformation of the amorphous layers resulted most probably from the strong constraint imposed by the slip deformation in the crystalline component to which amorphous component is intimately connected.

Citation Download Citation

Z. Bartczak, Andrzej Galeski, A. S. Argon, and R. E. Cohen "Plastic deformation of the amorphous component in semicrystalline polymers", Proc. SPIE 3095, X-Ray Investigations of Polymer Structures, (18 February 1997); https://doi.org/10.1117/12.267200

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available

Members: $17.00

Non-members: $21.00 ADD TO CART

PROCEEDINGS
14 PAGES

DOWNLOAD PAPER SAVE TO MY LIBRARY

GET CITATION

RIGHTS & PERMISSIONS

Get copyright permission Get copyright permission on Copyright Marketplace

KEYWORDS

Crystals

Scattering

Polymers

X-rays

Diffraction

Macromolecules

Molecules

Show All Keywords

Keywords/Phrases

Search In:

Publication Years