Inversion procedures for bound-free diatomic transition intensities: application to the PFOODR spectra of 7Li2

Valery S. Ivanov; V. B. Sovkov

doi:10.1117/12.267754

3 March 1997 Inversion procedures for bound-free diatomic transition intensities: application to the PFOODR spectra of ⁷Li₂

Valery S. Ivanov, V. B. Sovkov

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Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267754
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation

Abstract

The determination of molecular adiabatic potentials from spectroscopic experimental data is one of the leading problems in the theoretical molecular spectroscopy. The mostly elaborated methods to analyze structured continuums of diatomic molecules with this aim were developed in (repulsive potential) and in (attractive potential). They are based on the uniform harmonic approximation and applicable to those systems only, where the repulsive potential is steeper than the attractive one. New procedures for determining a repulsive or an attractive potential function and a function of the electronic transition moment operator from structured bound-free transition intensity data are described in this paper. These procedures are free from the restrictions of other known approaches to the problems under consideration and can be applied to any structured continuum.

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Valery S. Ivanov and V. B. Sovkov "Inversion procedures for bound-free diatomic transition intensities: application to the PFOODR spectra of ⁷Li₂", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); https://doi.org/10.1117/12.267754

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