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We report two kinds of method for preparing luminescent silicon films with quantum crystallites (QCs) structures: (1) Using laser annealing technique to crystallize ultrathin amorphous silicon layers which were constructed in a-Si:H/a-SiNx:H multiquantum well (MQW) structures. (2) Applying the layer-by-layer deposition technique to the growth of silicon QCs by varying the hydrogen plasma exposure time. The novel structures of these two types of QCs films were characterized by X-ray diffraction and Raman scattering spectroscopy. The room temperature visible photoluminescence (PL) from Si QCs with size of 4 nm or less has been observed in most of samples.
Kun-Ji Chen,Xinfan Huang,Maorui Chen,Weihua Shi,Zhifeng Li, andDuan Feng
"Luminescent Si quantum dots films: preparation and characterization", Proc. SPIE 2364, Second International Conference on Thin Film Physics and Applications, (26 October 1994); https://doi.org/10.1117/12.190736
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Kun-Ji Chen, Xinfan Huang, Maorui Chen, Weihua Shi, Zhifeng Li, Duan Feng, "Luminescent Si quantum dots films: preparation and characterization," Proc. SPIE 2364, Second International Conference on Thin Film Physics and Applications, (26 October 1994); https://doi.org/10.1117/12.190736