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The spectroscopic properties of F3+ ions in tetrahedral sites in garnets, together with the good packing of these sites around the dodecahedral position occupied by rare-earth ions, favor a very efficient energy transfer from Fe3+ to TM3+. Since Fe3+ does not introduce additional losses, this ion is a potential sensitizer for Tm3+ laser emission.
Voicu Lupei,Aurelia Lupei,S. Bonea,P. M. Nanau,Georges Boulon,Christian Pedrini,Alain Brenier, andMaria Jesus Elejalde Garcia
"Spectroscopic bases of performance enhancement of two-micron lasers by Fe3+ sensitization", Proc. SPIE 2206, High-Power Gas and Solid State Lasers, (16 August 1994); https://doi.org/10.1117/12.184619
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Voicu Lupei, Aurelia Lupei, S. Bonea, P. M. Nanau, Georges Boulon, Christian Pedrini, Alain Brenier, Maria Jesus Elejalde Garcia, "Spectroscopic bases of performance enhancement of two-micron lasers by Fe3+ sensitization," Proc. SPIE 2206, High-Power Gas and Solid State Lasers, (16 August 1994); https://doi.org/10.1117/12.184619