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A systematic study of the synthesis of modified PEO-based ionically conducting polymer electrolyte systems for utilization in electrochromic windows is reported. Copolymerization of ethylene oxide and various epoxy-functionalized monomers have produced polymers incorporating sidechains. These bulky functionalities inhibit crystallinity, and therefore, give rise to ionic conductivity levels which are two to three orders of magnitude higher than those of PEO at room temperature and below.
G. R. Davies,T. S. Mann,S. P. McNeeney, andD. Platt
"Solid polymer electrolyte suitable for large-area electrochromic applications", Proc. SPIE 1728, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Chromogenics for Smart Windows, (25 November 1992); https://doi.org/10.1117/12.130557
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G. R. Davies, T. S. Mann, S. P. McNeeney, D. Platt, "Solid polymer electrolyte suitable for large-area electrochromic applications," Proc. SPIE 1728, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Chromogenics for Smart Windows, (25 November 1992); https://doi.org/10.1117/12.130557