Self-luminescent BaMg2V2O8 and Sm3+ doped BaMg2V2O8 phosphors have been obtained by high temperature solid state reaction method. Detailed Structural and optical analysis were carried out and compare the result of pure and Sm doped samples for checking the suitability in various photonic applications. Broad emission band centered at 516 nm of BaMg2V2O8 , under near UV excitation arises due to 3T1→1A1 and 3T2→2A1 transition of (VO4) 3- and gives blue- green emission. Incorporation Sm3+ in to the luminescent host lattice leads to the enhancement of the emission intensity and color tuning ability of the host. The CIE chromaticity coordinates for BaMg2V2O8 gives a blue green emission following the coordinates (x, y) as (0.29, 0.43) and for Sm3+ doped BaMg2V2O8 show the yellow emission following the coordinates (x, y) as (0.36, 0.41).
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