Paper
31 May 1984 Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)x (X = 2,3,4)
A J Ouderkirk, T A Seder, Eric Weitz
Author Affiliations +
Proceedings Volume 0458, Applications of Lasers to Industrial Chemistry; (1984) https://doi.org/10.1117/12.939425
Event: 1984 Los Angeles Technical Symposium, 1984, Los Angeles, United States
Abstract
An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(C0)3 and Fe(C0)4 with CO are also reported. The photophysics of Fe(C0)x formation is discussed.
© (1984) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
A J Ouderkirk, T A Seder, and Eric Weitz "Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)x (X = 2,3,4)", Proc. SPIE 0458, Applications of Lasers to Industrial Chemistry, (31 May 1984); https://doi.org/10.1117/12.939425
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Cited by 2 scholarly publications.
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KEYWORDS
Absorption

Photolysis

Argon

Carbon monoxide

Excimer lasers

Metals

Gas lasers

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